Sorbonne • Alexandre Courac
High‑Pressure Materials Science

Alexandre Courac (Kurakevych) is Associate Professor (MCF) at Sorbonne University – IMPMC, where he conceptualizes and synthesizes new materials under extreme pressure–temperature conditions. His research combines in‑situ synchrotron diffraction and thermodynamic modeling to develop scalable pathways to superhard and optoelectronic solids, such as quasi‑direct band‑gap silicon allotropes. In 2017–2022 he was a member of the Institut Universitaire de France (IUF), leading the project Synthesis of Silicon Allotropes, which provided the first high‑purity crystals of hexagonal and clathrate phases and enabled systematic thermodynamic modeling of their stability. He was a principal investigator of the ANR project POLYCARBS (2017–2021), and is task leader in SUPERSTRONG (2022–2026) and BCSi (2021–2024).

Originated from the Crimea peninsual, he began research as a student at the Institute for Superhard Materials in Kiev, NAS of Ukraine (V. Solozhenko) and at the University of Hawaii high‑pressure group (M. Manghani & L.C. Ming), publishing his first articles during his Master’s (2002). His doctoral thesis (Université Paris Nord, 2007, funded by CNRS) on ultra‑hard boron–carbon–nitrogen–oxygen phases laid the foundation for his expertise in high‑pressure chemistry (director V. Solozhenko). From 2011 to 2013, he was postdoctoral fellow at Carnegie Institution of Washington (Geophysical Laboratory, now EPL), after ear lier CNRS postdoc and ATER positions in Paris (2007–2011). He obtained his HDR (Habilitation à Diriger des Recherches) in Physics at Université Pierre & Marie Curie / Paris 6 in 2017. Today his trajectory reflects continuity from fundamental phase diagrams to the design of functional crystals, training of young scientists, and leadership of international collaborations across Europe, the US, and Asia.

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Portrait of Alexandre Courac (Kurakevych)
@ A. Courac

Research

The contribution of A. Courac is internationally recognized in high-pressure high-temperature (HPHT) synthesis and high-pressure crystallography, working at the interface of solid-state chemistry, physics of materials, and crystallography. Major contributions to ultrahard light-element materials include the discovery of boron subnitride B₁₃N₂, first reported in Acta Crystallographica C, and key results on boron allotropy published in Nature (2009), including an allotrope exhibiting record hardness among boron polymorphs. Record performance in a non-carbon ultrahard material was established for nanostructured cubic boron nitride (nano-cBN) in Advanced Materials, accompanied by patents with IMPMC and followed by continued studies of structure–property relationships and phonon-related behavior. A second high-impact research direction emerged from the discovery of the high-pressure clathrate Na₄Si₂₄ (Crystal Growth & Design), which enabled the pathway toward the zeolite-type silicon allotrope Si₂₄, published in Nature Materials (2015) and supported by multiple patents. These results collectively position high pressure as a tool not only for accessing extreme states of matter, but also for delivering new crystal structures, compositions, and nanostructures with advanced mechanical and functional properties.

The research program is structured around three interdisciplinary axes that jointly enable rational materials discovery under pressure. (1) In situ crystallography: synchrotron X-ray diffraction under extreme conditions is used to identify transient intermediates, determine crystal structures and equations of state, and follow kinetics of transformations in real time, using large-volume presses and dedicated sample environments. These experiments are carried out with large-volume devices at IMPMC and through beamline campaigns at SOLEIL and the ESRF, where in situ diffraction can be combined with complementary measurements to constrain microstructure, texture, and stability fields. (2) Chemical thermodynamics: pressure-dependent phase stability and chemical reactivity are addressed through thermodynamic analysis and modelling, including CALPHAD/Thermo-Calc approaches, to build consistent descriptions of multicomponent systems (boron-rich ceramics, Si-based compounds) and to translate experimental constraints into predictive phase diagrams. (3) Phase transformations and crystal growth: emphasis is placed on mechanistic understanding—nucleation, growth, metastability, and recovery pathways—linking transformation sequences to final microstructures and to properties such as hardness, toughness, and electronic functionality. Across these axes, high pressure is treated as a quantitative variable that reshapes thermodynamics and reaction pathways, enabling the targeted synthesis of (i) new crystal structures, (ii) new compositions, and (iii) pressure-stabilized nanostructures. The portfolio spans ultrahard carbides/borides/nitrides and silicon allotropes of technological interest; synthesis outcomes—successful or not—are systematically leveraged to refine phase boundaries, constrain reaction routes, and guide next-generation experiments toward reproducible crystals and scalable synthesis windows.

Projects

ANR SUPERSTRONG — High‑Tc Cuprates

Role: Work Package Manager (2022–2026)

High‑pressure calorimetry and advanced thermodynamics to probe correlated electron systems in strongly overdoped cuprates. Method development is transferrable to semiconductors and superhard materials.
Publications & Highlights:
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ANR BCSi — BxCSiy Phases at HP–HT

Role: Work Package Manager (2021–2025)

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Team

1. PI & Senior Researchers / Engineers

Principal Investigator. Alexandre Courac (Kurakevych) — Associate Professor, Sorbonne University — IMPMC. Focus: HPHT synthesis; in‑situ synchrotron diffraction; CALPHAD; HP calorimetry.

  • Y. Le Godec — CNRS DR, thermodynamics & HP platforms
  • W. A. Crichton — ESRF, in‑situ synchrotron diffraction
  • B. Baptiste — IMPMC, crystallography
  • V. L. Solozhenko — LSPM, superhard materials
  • H. Moutaabbid — IMPMC, HP sample environments

2. Current PhD Candidates

  • Tassadit (Fatma) Sadmi (10/2024– ) — High‑pressure synthesis of new phases in B–C–Si–X system.

3. Current Postdocs

  • Vacant — HPHT synthesis (MCSI)
  • Vacant — HPHT calorimetry (ANR)

4. Master fellows


Recent fellows include:
  • Yannick De Macedo (M2, 2024) — HP in‑situ design of photovoltaic silicon forms.
  • Idris Akbaraly (M1, 2023) — In‑situ silicon studies.
  • Martin Demoucron (M2, 2022) — Si‑doped borides → PhD 2022–2025.
  • S.M. Dolatabadi Hamedi (M2, 2021) — Graphite intercalation compounds.
  • Nabil Amoura (M2, 2020; M1, 2018) — Carbides; silicon clathrates/allotropes.
  • Ruben De Barros (M2, 2019) — Graphite insertion compounds.
  • Ioannis Touloupas (M2, 2018) — Magnesium carbides.
  • Enguerrand Preval (M2, 2016) — Si24 synthesis.
  • Kamel Loukkas (M1, 2016) — Na–Si clathrate diagrams.
  • Azamat Khairullin (M1, 2016) — In‑situ resistivity, HP cells.
  • Abdelrahman Emam (M1, 2016) — Cubic Si136, optical characterization.
  • Umranee Rambhunjun (M1, 2013) — Thermodynamics of Mg–C system.

Alumni

PhD Alumni

  • Martin Demoucron (2022–2025) — PhD on B–C–Si–X HP synthesis; Postdoc at ESRF beamline from 01.01.2026.
  • Silvia Pandolfi (2016–2019) — Si‑based materials; now Associate Professor, SU (Besson Prize 2020).
  • Simon Delacroix (2016–2019) — Boron at the nanoscale; Postdoc, École Polytechnique.
  • Rémi Grosjean (2013–2016) — Boron nanomaterials; Project Manager, Swatch Group.
  • Fernando Igoa (2019–2022) — Geology‑inspired boron nanomaterials.
  • Zied Jouini (2014–2018) — Na–Si clathrates; Lecturer & Data Scientist R&D.

Postdoc Alumni

  • Carlos Renero‑Lecuna (2016–2017) — NaSi6 single crystals; Assoc. Prof., Bilbao Univ.
  • Lin Lin (2022–2023) — Si clathrates; Professor & Lab Director, Beihua Univ.
  • Jian Zhang (2022–2023) — Semiconductors under HP; Assoc. Prof., Beihua Univ.
  • Yixuan Zhao (2020–2021) — Carbides (ANR POLYCARBS); Data Scientist R&D.
  • Qiang Bian (2018–2019) — Ab initio carbides; Assoc. Prof., Guangdong Univ. Tech.

Master Alumni

  • Yannick De Macedo (M2, 2024) — HP in‑situ design of photovoltaic silicon forms.
  • Idris Akbaraly (M1, 2023) — In‑situ silicon studies.
  • Martin Demoucron (M2, 2022) — Si‑doped borides → PhD 2022–2025.
  • S.M. Dolatabadi Hamedi (M2, 2021) — Graphite intercalation compounds.
  • Nabil Amoura (M2, 2020; M1, 2018) — Carbides; silicon clathrates/allotropes.
  • Ruben De Barros (M2, 2019) — Graphite insertion compounds.
  • Ioannis Touloupas (M2, 2018) — Magnesium carbides.
  • Enguerrand Preval (M2, 2016) — Si24 synthesis.
  • Kamel Loukkas (M1, 2016) — Na–Si clathrate diagrams.
  • Azamat Khairullin (M1, 2016) — In‑situ resistivity, HP cells.
  • Abdelrahman Emam (M1, 2016) — Cubic Si136, optical characterization.
  • Umranee Rambhunjun (M1, 2013) — Thermodynamics of Mg–C system.

Teaching

ED297 — Scientific Integrity Training. At doctoral and Master levels, I deliver workshops on good research practices, authorship, data management, conflict‑of‑interest prevention, and responsible conduct in experimental design and reporting. Sessions combine case studies from materials science with checklists for lab notebooks, FAIR data, and preregistration when appropriate. Goal: align lab routines with institutional and EU guidance on integrity, reproducibility, and open science.

Professional Orientation (OIP). For L2–L3 students, active workshops on employability: timed self‑presentations, CV/cover‑letter clinics, interview rehearsals, and networking assignments (professional interviews prepared in class). These activities connect physics with job‑market expectations and help students articulate skills for internships and early careers.

Core Teaching — General Physics, Thermodynamics, Materials & Labs. Teaching in L1–L3 and supervision of L3 internships and M1/M2 theses in high‑pressure materials. Practical modules emphasize instrumentation (oscilloscopes, function generators, microcontrollers, sensors, video analysis) and reproducible analysis in Python. Evaluation is transparent and criterion‑based, fostering the translation of physical models into engineering practice.

Selected Publications

  1. Pandolfi, S.; Renero-Lecuna, C.; Le Godec, Y.; Baptiste, B.; Menguy, N.; Lazzeri, M.; Gervais, C.; Spektor, K.; Crichton, W. A.; Kurakevych, O. O.*
    Nature of Hexagonal Silicon Forming via High-Pressure Synthesis: Nanostructured Hexagonal 4H Polytype.
    Nano Letters 2018, 18 (9), 5989–5995. IF = 12.3; 49 citations (6.13/year). https://doi.org/10.1021/acs.nanolett.8b02816
    Discovery of high-purity nanostructured hexagonal Si-4H with strong visible-range photoluminescence. A PhD work under supervision of PI (IUF project).
  2. Patent US 10179740 — Strobel, T. A.; Kim, D. Y.; Kurakevych, O. O.
    Form of silicon and method of making the same.
    The invention relates to a new phase of silicon, Si24, and a method of making the same. It also relates to Na4Si24 and its synthesis.
  3. Kim, D. Y.; Stefanoski, S.; Kurakevych, O. O.; Strobel, T. A.
    Synthesis of an open-framework allotrope of silicon.
    Nature Materials 2015, 14 (2), 169–173. IF = 38.7; 168 citations (15.7/year). https://doi.org/10.1038/nmat4140
    Discovery of Si24 with superior optoelectronic properties. PI synthesized the phase and resolved its structure.

Novel Crystal Structures (powder XRD)

rhombohedral B13N2
1. Rhombohedral B13N2 (2007, cit. 130) — doiconfirmed by SC
diamond-like BC5
2. Diamond‑like BC5 (2009, cit. 311) — doi
graphite-like turbostratic BCx
3. Graphite‑like turbostratic BCx (2010, cit. 11) — doi
tetragonal pc-B52
4. Tetragonal pc‑B52 (2013, cit. 19) — doi
orthorhombic gamma B28
5. Orthorhombic γ‑B28 (2009, cit. 835) — doiconfirmed by SC
monoclinic beta Mg2C3
6. Monoclinic β‑Mg2C3 (2014, cit. 47) — doi
triclinic gamma Mg2C3
7. Triclinic γ‑Mg2C3 (2023, cit. 3) — doi
antifluorite Mg2C
8. Antifluorite Mg2C (2013, cit. 51) — doi
orthorhombic Si24
9. Orthorhombic Si24 (2015, cit. 266) — doiconfirmed by SC
orthorhombic NaSi6 (Na4Si24)
10. Orthorhombic NaSi6 (Na4Si24) (2013, cit. 78) — doiconfirmed by SC
Non-recoverable HP cold diamond BCxN
11. HP “cold diamond” structure of compressed graphitic BCxN, BCx & BN (2005, cit. 25) — doi
Hexagonal Si-4H (2018)
12. Hexagonal Si‑4H (2018, cit. 49) — doiconfirmed by SC

Contact

Email
alexandre.courac@sorbonne-universite.fr
Affiliation
IMPMC, Sorbonne University — Paris, France
Focus
HPHT synthesis • In‑situ XRD • CALPHAD • Silicon allotropes • Superhard materials • HP calorimetry